Download e-book for iPad: Advances in Dendritic Macromolecules : 1995 (Advances in by G.R. Newkome

By G.R. Newkome

ISBN-10: 008055265X

ISBN-13: 9780080552651

ISBN-10: 1559389397

ISBN-13: 9781559389396

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Extra resources for Advances in Dendritic Macromolecules : 1995 (Advances in Dendritic Macromolecules) (Advances in Dendritic Macromolecules)

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In 1992, De Gennes received the Nobel prize in physics for his studies on chaos Sind fractals. His results are relevant for the molecular design of cascade polymers especially in their threedimensional growth. A. Repetitive Synthesis Repetitive strategy is a fundamental principle for the synthesis of dendrimers, that was first coined, to the best of our knowledge in our seminal cascade paper. ^ It implies a repetitious sequence of the same reaction steps, as initially demonstrated in the synthesis of linear polyamines,^ by sequential Michael addition, followed by a facile nitrile reduction (Scheme 1).

Hawker, C. ; Pochan, J. ; Fr6chet, J. M. J. Macromolecules 1993, 26,1514. 44. ; White, J. W; Hawker, C. J,; Wooley, K. ; Fr6chet, J. M. J. 7. Phys. Chem. 1993,97, 293. This Page Intentionally Left Blank CASCADE MOLECULES: BUILDING BLOCKS, MULTIPLE FUNCTIONALIZATION, COMPLEXING UNITS, PHOTOSWITCHING Rolf Moors and Fritz VogtIe ABSTRACT I. INTRODUCTION A. Repetitive Synthesis II. TOSYLAMIDE CASCADES A. Divergent Synthetic Strategy B. Convergent Synthetic Strategy III. POLYAMINE DENDRIMERS A. Tris(2-aminoethyl)amine as Core Unit B.

Am. Chem. Soc 1989, 777, 2339. 33. Hawker, C. ; Frechet, J. M. J. Polymer 1992,33, 1507. 34. Wooley, K. ; Frechet, J. M. J. Unpublished results. 35. ; Wooley, K. ; Hawker, C. ; Frechet, J. M. J. Polym. Prep. 1991, 32, 631. 36. Gitsov, L; Wooley, K. ; Frechet, J. M. J. Angew. Chem. Int. Ed Engl. 1992, 31, 1200. 37. Gitsov, L; Wooley, K. ; Hawker, C. ; Ivanova, P T; Frdchet, J. M. J. Macrvmolecules 1993,26,5621. 38. Gitsov, L; Frechet, J. M. J. Unpublished results. 39. Mourey, T. ; Turner, S. ; Frechet, J.

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Advances in Dendritic Macromolecules : 1995 (Advances in Dendritic Macromolecules) (Advances in Dendritic Macromolecules) by G.R. Newkome

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