Download e-book for iPad: Advances in Carbohydrate Chemistry and Biochemistry, Vol. 59 by Derek Horton

By Derek Horton

ISBN-10: 0120072599

ISBN-13: 9780120072590

Considering the fact that its inception in 1945, this serial has supplied serious and integrating articles written by way of examine experts that combine business, analytical, and technological points of biochemistry, natural chemistry, and instrumentation technique within the examine of carbohydrates. The articles supply a definitive interpretation of the present prestige and destiny tendencies in carbohydrate chemistry and biochemistry. top of the range complete stories protecting all elements of carbohydrate chemistry

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The relative configuration at C-6 of the heptose was established by GLC of the corresponding d-glycero-d-altro-heptitol heptaacetate derivative and by 42 r. m. de lederkremer and c. gallo-rodriguez comparison with an authentic sample. 247 Occurrence. 248 Compound 49 has been identified as a component of the Gram-negative bacterium Chromobacterium violaceum,249 and unusually, in both ␣ and ␤-pyranosyl form250 in the O-specific polysaccharide of the LPS. Antigenic polysaccharides from the Gram-positive microorganism, Eubacterium saburreum, contain unusual structural features, for example d-glycero-d-galactoheptose, as a main constituent.

32 r. m. de lederkremer and c. gallo-rodriguez Occurrence. 167 Preparation. 168 Occurrence. 6-Deoxy-d-gulose (36) occurs in steroidal glycosides,160 for example, from the sap of the upas tree, Antiaris toxicaria,169 from the wallflower, Cheiranthus cheiri,170 and from Digitalis canariensis var. 171 Preparation. 6-Deoxy-d-gulose was originally prepared by the cyanohydrin synthesis from 5-deoxy-d-xylose. 172 naturally occurring monosaccharides 33 Occurrence. 173 Recently, an O-antigenic polysaccharide with the repeating unit 3)-Glc-(1→3)-6-d-Tal-(1→, was reported in B.

S. Besra, Mycobacterial arabinan biosynthesis: the use of synthetic arabinoside acceptors in the development of an arabinosyl transfer assay, Glycobiology, 7 (1997) 1121–1128. 23. P. J. Brennan and H. Nikaido, The envelope of mycobacteria, Annu. Rev. , 64 (1995) 29–63. 24. L. Galbraith and S. G. Wilkinson, Structures of the O21 and O25 antigens of Stenotrophomonas maltophilia, Carbohydr. , 323 (2000) 98–102; and references cited therein. 25. R. L. Whistler and J. N. BeMiller, Pentoses. ␤-d-Arabinose, Methods Carbohydr.

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Advances in Carbohydrate Chemistry and Biochemistry, Vol. 59 by Derek Horton

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